Wednesday, 23 September 2015

thermodynamics - How can -G/T and -A/T be thought of as 'disguised' entropies?


I understand that entropy is defined as dS=dq/T for a reversible change but I fail to see why G/T and A/T can be thought of as 'disguised' entropies. This is a question on my problem sheet at university and my tutor has hinted: "You need to think about the total entropy change for a process".



Answer



The fundamental equation of (chemical) thermodynamics ΔG=ΔHTΔS may be divided by
(-T):


ΔGT=ΔHsysT+ΔSsys


In this equation ΔHsysT is the entropy change of the system by “heat” exchange with the surroundings, hence ΔHsysT=ΔSsurroundings. On this basis, the above equation may be identified as:


ΔStotal=ΔSsurroundings+ΔSsys


ΔSsys and ΔSsurroundings strive mutually to a maximum of ΔStotal.


ΔG is a disguised entropy change, because ΔH is intrinsically an entropy change too, as explained above.



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