Wednesday, 29 July 2015

Gibbs free energy=potential free energy? (Transition state theory)


Online I found the plot Gibbs free energy vs. reaction coordinate:


https://en.wikipedia.org/wiki/Transition_state_theory


and on many books I found the plot potential energy vs. reaction coordinate (e.g. page 237 Atkins, Physical Chemistry for the Life Sciences, 2nd Ed).


In the first case activation energy is defined as ΔG, whereas in the second case is defined as difference of potential energy.


Thus is the Gibbs free energy a potential energy?


Thank you very much.





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