Saturday, 25 July 2015

thermodynamics - Why at constant pressure and temperature Gibbs energy change of a process can be negative?




  1. dG<0, for a spontaneous reaction at constant Temperature T and Pressure P, this means that at contant T and P, dG can be negative

  2. dG=VdPSdT, this means that at constant P (dP=0) and constant T (dT=0), dG=V0T0=0. At constant P and T according to this equation dG is always zero.


Statement 1 contradicts statement 2. Why does this happen?




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