Wednesday 21 September 2016

reaction mechanism - reference states for activities



I wanted to ask clarifications about a passage in Atkin's physical chemistry book, chapter 9, in the paragraph 9.2 description of equilibrium.


For studying equilibrium of a reaction, where $\nu_i$ are the stechiometric coefficients it imposes $\sum_i \nu_i \mu_i=0$ with $\mu$ the chemical coefficients. At this point it writes the chemical coefficients as a function of the activities $\mu_i=\mu_i^\circ+RT\ln(a_i)$ and identifies the term $\sum_i \nu_i \mu_i^\circ$ with the standard reaction Gibbs energy. I do not understand this identification. I thought that the standard state for the definition of activities (even dependent on wether the substance is a solute or a solvent) was not the same reference state for computing the reaction Gibbs energy (and does not depend on the role played by the substance in the reaction). I'm surely getting something wrong...




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