I wanted to ask clarifications about a passage in Atkin's physical chemistry book, chapter 9, in the paragraph 9.2 description of equilibrium.
For studying equilibrium of a reaction, where νi are the stechiometric coefficients it imposes ∑iνiμi=0 with μ the chemical coefficients. At this point it writes the chemical coefficients as a function of the activities μi=μ∘i+RTln(ai) and identifies the term ∑iνiμ∘i with the standard reaction Gibbs energy. I do not understand this identification. I thought that the standard state for the definition of activities (even dependent on wether the substance is a solute or a solvent) was not the same reference state for computing the reaction Gibbs energy (and does not depend on the role played by the substance in the reaction). I'm surely getting something wrong...
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