Saturday, 24 September 2016

redox - Why are electrons shared equally when calculating formal charge, but unequally when calculating oxidation state?



  • When calculating formal charge - electrons are shared equally between the atoms in the bond. enter image description here

  • When calculating oxidation state - electrons are both given to the most electronegative atom. enter image description here



Why is this different?


enter image description here


I am assuming it is something to do with the intended use of calculating formal charge and oxidation state, which I believe are:



  • Formal charge can be used to find the most stable structure.

  • Oxidation numbers can be used to determine what will become oxidised in a redox reaction.


However, even based on their uses, I am unsure why they are calculated differently.


*Images from Wikipedia





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