Friday 23 September 2016

entropy - Raoult's Law explained with thermodynamics/ free energy


I got some confusion going on with this explanation of Raoult's Law.


This is what my book say:



Because the ideal solution has a higher entropy than the pure solvent, the energy of a vapor increases as its molecules expand into a larger volume, that is, if they are at a lower pressure. Thus, solutes in a solution reduce the vapor pressure of the solvent.



Also, I should mention both solutions have the same $\Delta S$ based on the same $\frac{\Delta H}{T}$.


The point is I am confused about the last part of this explanation about how molecules expand. First off, this is all in a closed container, otherwise there's no vapor pressure. If so, the volume should be the same there is no larger or smaller volume.




No comments:

Post a Comment

readings - Appending 内 to a company name is read ない or うち?

For example, if I say マイクロソフト内のパートナーシップは強いです, is the 内 here read as うち or ない? Answer 「内」 in the form: 「Proper Noun + 内」 is always read 「ない...