Thursday, 7 July 2016

physical chemistry - Work done by the System


In thermodynamics work is defined as $~-p_{ex}\Delta V~$ for an ideal gas. If the total work is a negative value, that is in case of expansion of gas, we say that the work is done by the system and is negative.


I don't understand that why we use the pressure exerted on the gas in expression of work that is the external pressure and say that the work is done by the system ? If work is done by the system we should use internal pressure and if we use that in case of expansion the work done by the system will be positive which is contradicting. Please provide an explanation




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