For example, elemental iodine is deep violet. Its sigma bond or perhaps the lone pairs are capable of absorbing all visible light frequencies except violet which is why we see it as that color. Lithium, on the other hand, is red which means its valence electrons must be reflecting red frequencies. So, does that mean the valence/bonding electrons of IX2 are higher energy than the lithium valence electrons? In other words, is there a relationship between an orbitals energy and the type of light it can reflect?
You could perhaps compare IX2,SnXIIIX2, and SnXIVIX4, and which are violet, yellow, orange (in decreasing order of visible light energy).
Perhaps it has to do with symmetry? IX2 is D∞h, stannous iodide is C2v, and stannic iodide is Td.
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