Tuesday 10 May 2016

inorganic chemistry - Bond angle order of SF2, OF2, HOF



Arrange the following componds in the increasing order of bond angle. $$\ce{HOF,~OF2,~SF2}$$



I know that bond angle of $\ce{SF2}$ will be less than the bond angle of $\ce{OF2}$ because of larger size of sulfur atom.



How can I compare $\ce{HOF}$ with the other two? Since $\ce{H}$ is less electronegative than $\ce{O}$, the bond pair of $\ce{O - H}$ bond will be more closer to $\ce{O}$. The opposite happens for $\ce{O - F}$ bond. In $\ce{SF2}$ both bond pairs are near $\ce{F}$ so the bonds can come closer to each other.




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