Monday, 14 December 2015

physical chemistry - Find the pH of an amphiprotic salt dissolved in water at room temperature


Let's say I have a polyprotic acid HX2A with the following properties:



HX2AHAX+HX+K1=1101HAXAX2+HX+K2=1104


Now a 0.5 M solution of HAX is prepared; what will be the pH of the solution?


My textbook (and many other sources) says it should be


pK1+pK22


which sounds a little counterintuitive to me.


First of all, it implies that the pH is independent of the concentration of HAX present.


Also, if 1/pK1>pK2, then HAX should have the tendency to accept a HX+ more than it has of losing one, then why is the pH exactly partway between pK1 and pK2?




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