Let's say I have a polyprotic acid HX2A with the following properties:
HX2A−⇀↽−HAX−+HX+K1=1⋅10−1HAX−−⇀↽−AX2−+HX+K2=1⋅10−4
Now a 0.5 M solution of HAX− is prepared; what will be the pH of the solution?
My textbook (and many other sources) says it should be
pK1+pK22
which sounds a little counterintuitive to me.
First of all, it implies that the pH is independent of the concentration of HAX− present.
Also, if 1/pK1>pK2, then HAX− should have the tendency to accept a HX+ more than it has of losing one, then why is the pH exactly partway between pK1 and pK2?
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