Wednesday, 7 October 2015

experimental chemistry - Why a specific temperature for value of 1 calorie?


Everything in chemistry often comes with a strong reason and facts behind it, but I stuck in definition of 1 calorie.



My reference book define one calorie as amount of heat required to raise the temperature of one gram of water from 14.5 degrees Celsius to 15.5 degrees Celsius.


Why 14.5 and 15.5, why temperature such as 0 to 1 or 19 to 20 degree Celsius is not chosen?


Please forgive me if this question is too easy and I can't figure out the logic related to it.


I shall be glad to have your suggestions.



Answer




why temperature such as 0 or 1 degree celsius is not chosen??



That has been chosen by some.


According to Physical Laboratory Experiments: Part III.--Heat, 4th edition (1912) :




The following different calories should not be confused:




  1. ZERO DEGREE CALORIE:- The quantity of heat required to raise one gram of water from 0 [degrees] C to 1 [degree] C.




  2. ORDINARY CALORIE: cal.-The quantity of heat required to raise one gram of water from 15 [degrees] C to 16 [degree] C, this being taken as the mean room temperature.





  3. MEAN CALORIE OR ICE CALORIMETER CALORIE: The one-hundred part of heat required to raise one gram of water from 0 [degrees] C to 100 [degrees] C.




  4. ...





Heat capacity of liquid water is a continuously varying function of temperature itself, so a particular temperature or temperature interval must be specified. Various intervals were chosen historically, and when a small interval near 15 degrees C is chosen it is because that was thought of as room temperature 100-200 years ago.


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