Tuesday 20 October 2015

inorganic chemistry - Why isn't thallium triiodide stable?


We know that stability of higher oxidation state (+3) decreases and stability of lower oxidation state (+1) increases, so thallium is most stable in its +1 oxidation state due to the inert pair effect and paired s electrons.


In the compound $\ce{TlI3}$, since $\ce{I3}$ exists as a linear molecule $\ce{I3-}$ so the oxidation number of $\ce{Tl}$ is +1 which is stable and the compound should exist but I have read in many of the books that it does not exists. Why is it so?





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