Tuesday, 20 October 2015

inorganic chemistry - Why isn't thallium triiodide stable?


We know that stability of higher oxidation state (+3) decreases and stability of lower oxidation state (+1) increases, so thallium is most stable in its +1 oxidation state due to the inert pair effect and paired s electrons.


In the compound $\ce{TlI3}$, since $\ce{I3}$ exists as a linear molecule $\ce{I3-}$ so the oxidation number of $\ce{Tl}$ is +1 which is stable and the compound should exist but I have read in many of the books that it does not exists. Why is it so?





No comments:

Post a Comment

readings - Appending 内 to a company name is read ない or うち?

For example, if I say マイクロソフト内のパートナーシップは強いです, is the 内 here read as うち or ない? Answer 「内」 in the form: 「Proper Noun + 内」 is always read 「ない...