Thursday, 10 December 2015

Strong and weak acid


I know sulfuric acid is a strong acid and acetic acid is a weak acid. However when I write them in their chemical symbol.


Sulfuric acid: $\ce{H2SO4}$



Acetic acid: $\ce{CH3COOH}$


I realise that acetic acid has 4 atoms of hydrogen whereas sulfuric acid has only 2 atoms of hydrogen. So, shouldn't acetic acid be stronger than sulfuric acid?



Answer



Looking at the structures of those two acids might help. In both cases, the acidic hydrogens are part of hydroxyl groups. Because of polarity and the inductive effect, the O-H bond is weaker than C-H bonds which are very strong. As a result, it's nearly impossible for Carbon to lose a hydrogen without some kind of elimination reaction, whereas the O-H bond can autoprotolyze with other O-H bonds (even water). The weakness of the O-H bond is the basis for the acidity of those hydrogens. C-H bonds are essentially non-acidic, having pKa values around 45-50.


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