Friday, 2 December 2016

ph - Why do we neglect the protons from water's autoprotolysis?


Why don't we need to consider the $\ce{H+}$ ions of water when finding the $\ce{pH}$ of $0.01~\mathrm{M}$ of $\ce{HCl}$ solution?



The $\ce{pH}$ value of something is depending on the molarity of $\ce{H+}$ ions. But the teachers says the calculation is just $-\log(0.01)$, don't we need to consider the $\ce{H+}$ ions of water?



Answer



You could consider them, but what would be the result?


$0.01 M$ of $\ce{HCl}$ with $1\times10^{-7} M$ of $\ce{H^+}$ from water gives you $0.0100001 M$ of $H^+$. Find the pH of this concentration of $\ce{H^+}$ and compare with the pH you would obtain if you used $0.01 M$ directly.


You shouldn't see that the resulting pH differ significantly.


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