Thursday, 24 November 2016

inorganic chemistry - Why does Bismuth only create a +3 ion instead of a +5 ion?


It has 5 valence electrons, but only loses 3 of them to make a +3 ion. Why does this occur?


I believe it may have something to do with how losing 3 electrons leaves you with the p sublevel full, but I do not understand why Bismuth is okay with that.



Answer



Isn't it just that +5 is a lot of (positive) charge for a single cation? Which other (transition) metals do form a MX5+ cation? Just out of my mind, I can't think of any.


Typically, these high oxidation states exist in the form of oxo-anions (CrOX4X, MnOX4X, VOX4X3, etc.) and bismuth is no exception here: Bi(V) exists as bismutate (BiOX3X).


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