Saturday, 25 April 2015

inorganic chemistry - How can the electronic structure of pentaaquanitrosyliron be explained?



The magnetic moment of [Fe(HX2O)X5NO]X2+ is 3.87 Bohr magneton, which implies that there are 3 unpaired electrons. Since iron is in +1 oxidation state (due to charge transfer with nitrosyl group), it's electronic configuration is [Ar] 3d7. Having 3 unpaired electron is only possible if the 4th and 5th electron enter the higher energy orbital eg (crystal field theory). The t2g or the lower energy orbital has 5 electrons. Why do the 4th and 5th electron enter eg despite a strong field ligand (nitrosyl group) being present?




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readings - Appending 内 to a company name is read ない or うち?

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