Saturday, 25 April 2015

inorganic chemistry - How can the electronic structure of pentaaquanitrosyliron be explained?



The magnetic moment of $\ce{[Fe(H2O)5NO]^2+}$ is 3.87 Bohr magneton, which implies that there are 3 unpaired electrons. Since iron is in $+1$ oxidation state (due to charge transfer with nitrosyl group), it's electronic configuration is $[\ce{Ar}]\ \mathrm{3d^7}$. Having 3 unpaired electron is only possible if the 4th and 5th electron enter the higher energy orbital $\mathrm{e_g}$ (crystal field theory). The $\mathrm{t_{2g}}$ or the lower energy orbital has 5 electrons. Why do the 4th and 5th electron enter $\mathrm{e_g}$ despite a strong field ligand (nitrosyl group) being present?




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