Saturday 18 June 2016

physical chemistry - Law of Mass action VS Rate law



The Law of mass action has 2 parts - the equilibrium rate part & the reaction rate part. The "reaction rate part" states that rate of a reaction is directly proportional to the product of active masses of the reactants with each reactant term raised to it's stoichiometric coefficient. The rate law states that rate of a reaction is directly proportional to the product of active masses of the reactants with each reactant term raised to some power which may or may not be equal to stoichiometric coefficient of the reactant.


Why are the two laws different when in fact we are talking about the powers to which active masses of reactants should be raised in both the cases ? And which law is correct?




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