The correct order of melting point of alkali metal halides is:
- $\ce{MF}>\ce{MCl}>\ce{MBr}>\ce{MI}$
- $\ce{MI}>\ce{MBr}>\ce{MCl}>\ce{MF}$
- $\ce{MCl}>\ce{MF}>\ce{MBr}>\ce{MI}$
- $\ce{MI}>\ce{MF}>\ce{MCl}>\ce{MBr}$
The correct answer to this is option (1), the reason I could think of is that as the size of anion in ionic compound increases the covalent character increases and hence the melting point decreases.
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