Friday, 20 November 2015

inorganic chemistry - Melting points of alkali metal halides



The correct order of melting point of alkali metal halides is:



  1. $\ce{MF}>\ce{MCl}>\ce{MBr}>\ce{MI}$

  2. $\ce{MI}>\ce{MBr}>\ce{MCl}>\ce{MF}$

  3. $\ce{MCl}>\ce{MF}>\ce{MBr}>\ce{MI}$

  4. $\ce{MI}>\ce{MF}>\ce{MCl}>\ce{MBr}$




The correct answer to this is option (1), the reason I could think of is that as the size of anion in ionic compound increases the covalent character increases and hence the melting point decreases.




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