Friday, 20 November 2015

How is it determined how many electrons are transferred in redox reactions?


For example, iron and tin(II) sulfate will react to produce iron(II) sulfate and tin:


$\ce{Fe + SnSO4 -> FeSO4 + Sn}$


With the following half equations:


$\ce{Fe + SO4^{2-} -> FeSO4 + 2e-}$


and


$\ce{Sn^{2+} + 2e- -> Sn}$


but where does the "2" come from? Why can't it be:


$\ce{Fe + SO4^{5-} -> FeSO4 + 5e-}$


and



$\ce{Sn^{5+} + 5e- -> Sn}$




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