I have the following equation
Ka=cα21−α,
with units c=mol/cm3 and α is the same. I'm not sure how to get the correct units for Ka. What I have come up with so far is
Ka=mol2/cm6.
Answer
Andselisk correctly identified the law of dilution and the name Ostwald is often connected with it.
Kdissociation=α21−α⋅c
It is derived from the Law of mass action; the derivation can be found on Wikipedia and various other sources.
In principle there is no fixed unit for the (generalised) equilibrium constant, as it is simply defined as a product of the involved quantities according to the IUPAC gold book.
Equilibrium Constant
Quantity characterizing the equilibrium of a chemical reaction and defined by an expression of the type Kx=ΠBxνBB,where νB is the stoichiometric number of a reactant (negative) or product (positive) for the reaction and x stands for a quantity which can be the equilibrium value either of pressure, fugacity, amount concentration, amount fraction, molality, relative activity or reciprocal absolute activity defining the pressure based, fugacity based, concentration based, amount fraction based, molality based, relative activity based or standard equilibrium constant (then denoted K∘ ), respectively.
The standard equilibrium constant is always dimensionless, as it is defined differently (IUPAC gold book).
Standard Equilibrium Constant K, K∘
(Synonym: thermodynamic equilibrium constant)
Quantity defined by K∘=exp{−ΔrG∘RT}where ΔrG∘ is the standard reaction Gibbs energy, R the gas constant and T the thermodynamic temperature. Some chemists prefer the name thermodynamic equilibrium constant and the symbol K.
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