Saturday, 21 March 2015

What is the correct unit for the equilibrium constant?


I have the following equation


$$K_a = \dfrac{c\alpha^2}{1-\alpha},$$


with units $c= \pu{mol/cm^3}$ and $\alpha$ is the same. I'm not sure how to get the correct units for $K_a$. What I have come up with so far is


$$K_a= \pu{mol^2/cm^6}.$$



Answer



Andselisk correctly identified the law of dilution and the name Ostwald is often connected with it.
$$K_\text{dissociation} = \frac{\alpha^2}{1-\alpha}\cdot c$$ However, the degree of dissociation is $\alpha$ and has "no" unit, i.e. dimensionless quantity. Therefore the unit for the equilibrium constant is that of a concentration, in SI that would be $\pu{mol m-3}$.


It is derived from the Law of mass action; the derivation can be found on Wikipedia and various other sources.





In principle there is no fixed unit for the (generalised) equilibrium constant, as it is simply defined as a product of the involved quantities according to the IUPAC gold book.



Equilibrium Constant
Quantity characterizing the equilibrium of a chemical reaction and defined by an expression of the type $$K_x = \Pi_B x_B^{\nu_B},$$ where $\nu_B$ is the stoichiometric number of a reactant (negative) or product (positive) for the reaction and $x$ stands for a quantity which can be the equilibrium value either of pressure, fugacity, amount concentration, amount fraction, molality, relative activity or reciprocal absolute activity defining the pressure based, fugacity based, concentration based, amount fraction based, molality based, relative activity based or standard equilibrium constant (then denoted $K^\circ$ ), respectively.



The standard equilibrium constant is always dimensionless, as it is defined differently (IUPAC gold book).



Standard Equilibrium Constant $K$, $K^\circ$
(Synonym: thermodynamic equilibrium constant)
Quantity defined by $$K^\circ = \exp\left\{-\frac{\Delta_rG^\circ}{\mathcal{R}T}\right\}$$ where $\Delta_rG^\circ$ is the standard reaction Gibbs energy, $\mathcal{R}$ the gas constant and $T$ the thermodynamic temperature. Some chemists prefer the name thermodynamic equilibrium constant and the symbol $K$.




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