Sunday, 22 March 2015

organic chemistry - Migratory aptitude in Baeyer-Villiger reaction


In short, I do not understand how or why the migratory aptitude is as listed in every textbook I've read.


Firstly, they talk about a positive charge being built up that is stabilised by the movement of the most substituted group.


I cannot fathom such a build up in my mechanisms.


Please help me understand this in a mechanistic fashion.




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