Saturday, 9 April 2016

aromatic compounds - What is the origin of the colour of azo dyes?



Is it the same reason as to why transition metal complexes have colour?



Answer



Yes, it is all about the absorption of light at specific wavelength.


enter image description here


Azobenzene, the parent compound has an absorption maximum around $\lambda$= 430 nm in the visible spectrum.


The interesting part is: The absorption can be tuned by substitution of the arenes. This is done before the azo coupling.


azo dyes


Some examples are Allura Red (1), Chrysoine Resorcinol (2), Janus Green B (3) and Direct Blue 1 (4).


The colours of the molecules are chosen to resemble the colour in solution.


In order to make the dyes soluble in water, either sulfonate groups are attached or the dye molecule is just one fat cation.



As already mentioned by GM in another answer, +M substituents elongate the $\pi$ system (auxochromic effect).


No comments:

Post a Comment

readings - Appending 内 to a company name is read ない or うち?

For example, if I say マイクロソフト内のパートナーシップは強いです, is the 内 here read as うち or ない? Answer 「内」 in the form: 「Proper Noun + 内」 is always read 「ない...