Tuesday, 1 March 2016

organic chemistry - Reactions of phloroglucinol


Does phloroglucinol respond to the



  • iodoform test?

  • cerric ammonium nitrate test?

  • 2,4-DNP test?


I couldn't find any good sources that answer any of these.


I thought of this:





  1. Tautomerism can "change" phloroglucinol to a 1,3,5-triketone, which should respond to the iodoform test.




  2. It is a phenol, so it should respond to the cerric ammonium nitrate test.




  3. Again, the keto form should respond positively to the dinitrophenylhydrazine test.







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