Sunday, 27 March 2016

organic chemistry - What is the rationale of the IUPAC name for DDT?


The structure of DDT is


enter image description here


One of the benzene molecules should be the parent chain as it has a greater number of carbon atoms than the straight chain (which has just two carbon atoms). Taking benzene as the parent chain, I think that the name of the compound should be 1-Chloro-4-((1'-(4"-chlorophenyl))-2',2',2'-tricholoroethyl) benzene.



But the Wikipedia article states that the IUPAC name of the compound is 1,1,1-Trichloro-2,2-bis(4-chlorophenyl)ethane.


Why is the ethyl chain taken as the parent chain when it has lesser number of carbon atoms than the benzene ring?




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