Saturday, 16 January 2016

electronic configuration - Molecular orbital (MO) diagram for N2 and N2^-


I have been taught that the MO diagram is different for molecules with 14 or less electrons than the one used for molecules with 15 or more electrons.



For NX2 the orbitals in increasing energy are:


σ1s<σ1s<σ2s<σ2s<π2px,π2py<σ2pz<π2px,π2py<σ2pz


because it has 14 electrons.


For NX2X there are 15 electrons. Will the MO diagram be the same as that of NX2 or not? Why?


And because this is a good chance to ask, why is there this difference in orbital energies anyway?




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