Monday 2 January 2017

homework - When Z>1 are repulsive forces dominant or are attractive forces dominant?



According to PVreal = ZRT


If z >1 repulsive forces are dominant or are attractive forces? Different teachers are telling contradictory answers and after referring a few books, I have become more confused.


Points for ATTRACTIVE FORCES are dominant:



  • At high pressure the molecules do not strike the walls with full impact as they are dragged back by attractive forces.

  • When molecules are farther away from each other(as Vreal > Videal) the attractive forces are dominant.

  • Repulsive force are dominant when he molecules are almost in contact .


Points for REPULSIVE FORCES are dominant:




  • At high pressure the molecules are close each other that attractive forces are negligible but molecular size is significant.Thus repulsive forces are significant

  • As volume of real gas is more than volume of ideal gas , the real gas is more difficult to compress.Thus repulsive forces are dominating.


There was a question where P = 12atm T = 350K and Z = 1.2(after calculation). It was given that repulsive force are dominant.But my teacher said it was wrong and it should be attractive forces.




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