Wednesday, 4 January 2017

bond - Why does Nitrogen form N₂ (and not N₄) while but Phosphorus forms P₄ (and not P₂)?



NX2 is a gas
PX4 is a solid
N and P are in the same group in the periodic table


The bond enthalpies are:
NN triple bond is 949 kJ/mol


PP triple bond is 490 kJ/mol


PP single bond is 200 kJ/mol


NN single bond is 159296 kJ/mol


So why does P go to PX4 not PX2 and why does N go to NX2 and not NX4?




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