Monday 2 January 2017

bond - Physical intuition behind negative values for wave function?


So a positive and a positive wave function create a bonding orbital where the probability of finding an electron is summed while a positive and a negative create an anti-bonding orbital with a lower electron probability in the region between them leading to a repulsion. My confusion stems from not having any idea as to what a negative wave function is representing - can anyone give me some physical intuition on how this negative wave function could be correlated to something in reality?


(I tried asking this question on physics.SE but it would seem that in physics you just don't talk about or use the wave function until after you square it)




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