Tuesday, 15 March 2016

electrochemistry - Why is current non-zero when applied potential is still below E$^0$ in cyclic voltammetry?


In this diagram (Evans et al., J. Chem. Edu.) the current is non-zero, but the potential is still below the normal potential. How can the compound become oxidized at the working electrode, when the applied potential is still below the normal potential of the compound?


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