Thursday, 4 August 2016

inorganic chemistry - How is the triferric tetroxide of iron possible?


If oxygen has a valency of $-2$, $4$ of it would result in $-8$. But iron doesn't have a (variable) valency of anything that goes to $-8$. Then how is $\ce{Fe3O4}$ possible?



Answer



Iron, like many of the Transition Metals does have a variable valency, it can valencies of 2+ (ferrous iron), 3+ (ferric iron) and in some cases, 4+ (tetravalent iron).



In regards to $\ce{Fe3O4}$, according to the Wikipedia page Iron(II,III) oxide,



contains both $\ce{Fe^2+}$ and $\ce{Fe^3+}$ ions



A 2-dimensional diagram of $\ce{Fe3O4}$ is below, from the relevant ChemSpider page:


enter image description here


A 3-dimensional model is below (from Wikipedia):


enter image description here


red indicate oxygen


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