Thursday, 6 August 2015

electronic configuration - Find the valences of Z=26


I've tried this: enter image description here


But its hows that the valence of Fe in normal state is 4, when in the periodic table it isn't. Why does this happen? Can you show me the answer with configuration formula in the states with energy?



Answer



Hint: $$_{26}Fe\equiv1s^22s^22p^63s^23p^64s^23d^6\equiv [Ar]\ce{\underbrace{ ^ v }_{4s^2} \underbrace{ ^ v ,\;^ ,\;^ ,\;^ ,\;^ }_{3d^6} }$$ Think now what will be the configuration after losing electrons:


Spoiler:



! $$Fe^{2+}\to[Ar]\ce{\underbrace{ - }_{4s^2} \underbrace{ ^ v ,\;^ ,\;^ ,\;^ ,\;^ }_{3d^6}=[Ar]\underbrace{ ^ }_{4s^2} \underbrace{ ^ ,\;^ ,\;^ ,\;^ ,\;^ }_{3d^6} }$$


! $$Fe^{3+}\to[Ar]\ce{\underbrace{ - }_{4s^2} \underbrace{ ^ ,\;^ ,\;^ ,\;^ ,\;^ }_{3d^6} } $$




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