Saturday 13 June 2015

spectroscopy - How can I deduce the linearity of XeF2 from the IR spectrum?


The vibrational modes of $\ce{XeF2}$ are at $555$, $515$, and $213~\mathrm{cm^{-1}}$ but only two are IR active. Explain why this is consistent with $\ce{XeF2}$ having a linear structure.


From what I know, since it has $3$ atoms it should have $3n - 5$ vibrational modes, thus $3(3) - 5 = 4$ modes. Yet the problem tells me it only has $3$, which would suggest a non-linear shape. How to explain this?




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